I have worked a lot with the restoration and replication of antique glazed ceramics, especially architectural (usually called terracotta, sometimes faience). The damaging process is actually called 'freeze thaw' and there are actually few regions where this is a problem. A hard frost traps moisture in the material and a sudden thaw causes a physical imbalance and 'spalling' . There is an actual engineering test for freeze/thaw resistance, but with Mexican products it is as much a problem with consistency - standards are not followed from region to region, or even day to day.
I have had good results matching glazes with a special custom made epoxy putty, and a special (aliphatic) urethane coatings. This forms a UV resistant, 100% waterproof barrier - but these are toxic and extremely difficult to work with chemicals. You also have to make sure moisture cannot enter from the rear of the ceramics - another specialised field.
If I were to make a "hand painted Mexican look" mural today, and this again a highly personalised option, I would paint it on plaster, photograph it, and then photo transfer to architecturally rated tiles.
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